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[5-Chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

ABSTRACT: In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal-bipyramidal geometry. In the ligand, the hy-droxy group is involved in an intra-molecular O-H?N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5?(1)°. In the crystal, weak inter-molecular C-H?O hydrogen bonds and ?-? inter-actions between the aromatic rings [centroid-centroid distance = 3.816?(3)?Å] link the mol-ecules into centrosymmetric dimers.

SUBMITTER: Zhang X

PROVIDER: S-EPMC3212120 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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[5-Chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

Zhang Xiuyun X Yue Caihong C Yin Handong H

Acta crystallographica. Section E, Structure reports online 20110706 Pt 8

In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal-bipyramidal geometry. In the ligand, the hy-droxy group is involved in an intra-molecular O-H⋯N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5 (1)°. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds and π-π inter-act ...[more]

PMID: 22090822

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cis-(Dimethyl sulfoxide-?O)[N'-(3-eth-oxy-2-oxidobenzyl-idene-?O)-2-hy-droxy-benzohydrazidato-?N',O]dioxido-molybdenum(VI).

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