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Catena-Poly[[tetra-aqua-manganese(II)]-?-5-carboxyl-ato-1-carboxyl-atomethyl-2-oxidopyridinium-?O:O].

ABSTRACT: In the title coordination polymer, [Mn(C(8)H(5)NO(5))(H(2)O)(4)](n), the Mn(II) atom is coordinated by two carboxyl-ate O atoms from two 5-carboxyl-ato-1-carboxyl-atomethyl-2-oxidopyridinium (L(2-)) ligands and by four water mol-ecules in a distorted octa-hedral geometry. The L(2-) ligands bridge the Mn atoms into an infinite chain motif along [100]; the chains are further inter-linked by O-H?O hydrogen bonds into a three-dimensional supra-molecular net.

SUBMITTER: Yuan HY

PROVIDER: S-EPMC3212127 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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catena-Poly[[tetra-aqua-manganese(II)]-μ-5-carboxyl-ato-1-carboxyl-atomethyl-2-oxidopyridinium-κO:O].

Yuan Hong-Yan HY Jiang Mei-Xiang MX Feng Yun-Long YL

Acta crystallographica. Section E, Structure reports online 20110706 Pt 8

In the title coordination polymer, [Mn(C(8)H(5)NO(5))(H(2)O)(4)](n), the Mn(II) atom is coordinated by two carboxyl-ate O atoms from two 5-carboxyl-ato-1-carboxyl-atomethyl-2-oxidopyridinium (L(2-)) ligands and by four water mol-ecules in a distorted octa-hedral geometry. The L(2-) ligands bridge the Mn atoms into an infinite chain motif along [100]; the chains are further inter-linked by O-H⋯O hydrogen bonds into a three-dimensional supra-molecular net. ...[more]

PMID: 22090829

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