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Bis[2,6-bis-(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-?(3)-iodido-diiodidotetra-copper(I).

ABSTRACT: In the title centrosymmetric tetra-nuclear complex, [Cu(4)I(4)(C(15)H(17)N(5))(2)], the two distinct Cu(I) atoms adopt similar tetra-hedral arrangements, each being ligated by two I atoms, and two N atoms from one 2,6-bis-(3,5-dimethyl-1H-pyrazol-1-yl)pyridine ligand. In the crystal, there are no hydrogen bonds present, and only very weak ?-? inter-actions are observed [centroid-centroid distance = 3.985?(4)?Å], which connect neighbouring tetra-nuclear units into a chain motif along the b axis.

SUBMITTER: Jia CX 

PROVIDER: S-EPMC3212142 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Bis[2,6-bis-(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetra-copper(I).

Jia Chun-Xiao CX  

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

In the title centrosymmetric tetra-nuclear complex, [Cu(4)I(4)(C(15)H(17)N(5))(2)], the two distinct Cu(I) atoms adopt similar tetra-hedral arrangements, each being ligated by two I atoms, and two N atoms from one 2,6-bis-(3,5-dimethyl-1H-pyrazol-1-yl)pyridine ligand. In the crystal, there are no hydrogen bonds present, and only very weak π-π inter-actions are observed [centroid-centroid distance = 3.985 (4) Å], which connect neighbouring tetra-nuclear units into a chain motif along the b axis. ...[more]

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