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[2-(1H-Benzimidazol-2-yl-?N)aniline-?N]dichloridozinc.

ABSTRACT: In the title benzimidazole mononuclear complex, [ZnCl(2)(C(13)H(11)N(3))], the Zn(II) ion is four-coordinated in a distorted tetra-hedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57?(1)°. In the crystal, mol-ecules are linked by weak N-H?Cl hydrogen bonds into layers parallel to the bc plane. ?-? inter-actions with centroid-centroid distances in the range 3.4452?(8)-3.8074?(8)?Å are also observed.

SUBMITTER: Eltayeb NE

PROVIDER: S-EPMC3212144 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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[2-(1H-Benzimidazol-2-yl-κN)aniline-κN]dichloridozinc.

Eltayeb Naser Eltaher NE Teoh Siang Guan SG Chantrapromma Suchada S Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

In the title benzimidazole mononuclear complex, [ZnCl(2)(C(13)H(11)N(3))], the Zn(II) ion is four-coordinated in a distorted tetra-hedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57 (1)°. In the crystal, mol-ecules are linked by weak N-H⋯Cl hydrogen bonds into layers parallel to the bc plane. π-π inter-actions with centroid-centroid distances in the range 3.4452 (8)-3.8074 (8) Å are also observed. ...[more]

PMID: 22090846

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