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Tetra-aqua-bis-[4-(4H-1,2,4-triazol-4-yl)benzoato-?N]manganese(II) deca-hydrate.

ABSTRACT: In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol-ecules in a distorted octa-hedral geometry. The Mn(II) ion and two coordinated water mol-ecules lie on a twofold rotation axis. The water mol-ecules are involved in O-H?N and O-H?O hydrogen bonds with the triazole N atoms and carboxyl-ate O atoms, yielding a three-dimensional supra-molecular network. ?-? inter-actions between the benzene rings [centroid-centroid distance = 3.836?(9)?Å] are observed.

SUBMITTER: Piao YA 

PROVIDER: S-EPMC3212150 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis-[4-(4H-1,2,4-triazol-4-yl)benzoato-κN]manganese(II) deca-hydrate.

Piao Ying-Ai YA   Xuan Zhen-Yu ZY  

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol-ecules in a distorted octa-hedral geometry. The Mn(II) ion and two coordinated water mol-ecules lie on a twofold rotation axis. The water mol-ecules are involved in O-H⋯N and O-H⋯O hydrogen bonds with the triazole N atoms and carboxyl-ate O atoms, yielding a three-dimensional supra-molecular network. π-π inter-actio  ...[more]

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