Ontology highlight
ABSTRACT:
SUBMITTER: Li HF
PROVIDER: S-EPMC3212167 | biostudies-literature | 2011 Aug
REPOSITORIES: biostudies-literature
Li Hong-Fang HF Zhao Qi-Hua QH Xie Ming-Jin MJ Yang Fan F
Acta crystallographica. Section E, Structure reports online 20110716 Pt 8
In the bimetallic cyanide-bridged title complex, [Fe(0.98)HoRu(0.02)(CN)(6)(C(3)H(7)NO)(4)(H(2)O)(3)]·H(2)O, the Ho(III) ion is in a slightly distorted square-anti-prismatic arrangement formed by seven O atoms from four dimethyl-formamide (DMF) mol-ecules and three water mol-ecules, and one N atom from a bridging cyanide group connected with the Fe(III) atom which is octa-hedrally coordinated by six cyanide groups. In the crystal, mol-ecules are held together through O-H⋯N and O-H⋯O hydrogen-bon ...[more]