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N-(Quinolin-8-yl)ferrocene-1-carbox-amide.

ABSTRACT: In the title compound, [Fe(C(5)H(5))(C(15)H(11)N(2)O)], the cyclo-penta-dienyl rings are essentially eclipsed, and the dihedral angle between the cyclo-penta-dienyl ring planes is 0.632?(10)°. The Fe atom is slightly closer to the substituted cyclo-penta-dienyl ring, with an Fe-centroid distance of 1.6374?(3)?Å [1.6494?(3)?Å for the unsubstituted ring]. The amide group is essentially coplanar with the substituted cyclo-penta-dienyl ring, with an N-C(O)-C-C torsion angle of 2.3?(3)°.

SUBMITTER: Li X

PROVIDER: S-EPMC3212180 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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N-(Quinolin-8-yl)ferrocene-1-carbox-amide.

Li Xia X Du Ling-Zhi LZ

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

In the title compound, [Fe(C(5)H(5))(C(15)H(11)N(2)O)], the cyclo-penta-dienyl rings are essentially eclipsed, and the dihedral angle between the cyclo-penta-dienyl ring planes is 0.632 (10)°. The Fe atom is slightly closer to the substituted cyclo-penta-dienyl ring, with an Fe-centroid distance of 1.6374 (3) Å [1.6494 (3) Å for the unsubstituted ring]. The amide group is essentially coplanar with the substituted cyclo-penta-dienyl ring, with an N-C(O)-C-C torsion angle of 2.3 (3)°. ...[more]

PMID: 22090882

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