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{?-1,2-Bis[bis(4-meth-oxy-phen-yl)phosphan-yl]-1,2-dimethyl-hydrazine-?P:P'}bis-[chloridogold(I)] tetra-hydro-furan disolvate.


ABSTRACT: The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P-Au-Cl = 175.68?(3)?Å]. The nuclei are 3.122?(2)?Å apart. The mol-ecule exhibits a twofold rotation axis.

SUBMITTER: Kriel FH 

PROVIDER: S-EPMC3212261 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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{μ-1,2-Bis[bis(4-meth-oxy-phen-yl)phosphan-yl]-1,2-dimethyl-hydrazine-κP:P'}bis-[chloridogold(I)] tetra-hydro-furan disolvate.

Kriel Frederik H FH   Fernandes Manuel A MA   Coates Judy J  

Acta crystallographica. Section E, Structure reports online 20110730 Pt 8


The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P-Au-Cl = 175.68 (3) Å]. The nuclei are 3.122 (2) Å apart. The mol-ecule exhibits a twofold rotation axis. ...[more]

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