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1-Diazo-naphthalen-2(1H)-one.

ABSTRACT: The mol-ecule of the title compound, C(10)H(6)N(2)O, is nearly planar [maximum deviation = 0.030?(1)?Å]. The CN(2) moiety is almost linear, with a C-N-N angle of 175.50?(14)°. A single inter-molecular C-H?O hydrogen bond is observed in the crystal structure. A ?-? inter-action is also observed with the shortest distance being 3.6832?(12)?Å between the the centroids of the six-membered rings.

SUBMITTER: Kitamura M

PROVIDER: S-EPMC3212336 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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1-Diazo-naphthalen-2(1H)-one.

Kitamura Mitsuru M Sakata Rie R Matsumoto Taisuke T

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

The mol-ecule of the title compound, C(10)H(6)N(2)O, is nearly planar [maximum deviation = 0.030 (1) Å]. The CN(2) moiety is almost linear, with a C-N-N angle of 175.50 (14)°. A single inter-molecular C-H⋯O hydrogen bond is observed in the crystal structure. A π-π inter-action is also observed with the shortest distance being 3.6832 (12) Å between the the centroids of the six-membered rings. ...[more]

PMID: 22090993

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