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1,3-Diallyl-6-bromo-1H-imidazo[4,5-b]pyridin-2(3H)-one.

ABSTRACT: In the mol-ecule of the title compound, C(12)H(12)BrN(3)O, the fused-ring system is essentially planar, the largest deviation from the mean plane being 0.0148?(3)?Å. The two allyl groups are nearly perpendicular to the imidazo[4,5-b]pyridine plane [C-C-N-C torsion angles of 81.6?(4) and -77.2?(4)°] and point in the same direction. The planes through the atoms forming each allyl group are nearly perpendicular to the imidazo[4,5-b]pyridin-2-one system, as indicated by the dihedral angles between them of 80.8?(5) and 73.6?(5)°.

SUBMITTER: Dahmani S

PROVIDER: S-EPMC3213442 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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1,3-Diallyl-6-bromo-1H-imidazo[4,5-b]pyridin-2(3H)-one.

Dahmani Siham S Kandri Rodi Youssef Y Luis Santiago V SV Bolte Michael M El Ammari Lahcen L

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

In the mol-ecule of the title compound, C(12)H(12)BrN(3)O, the fused-ring system is essentially planar, the largest deviation from the mean plane being 0.0148 (3) Å. The two allyl groups are nearly perpendicular to the imidazo[4,5-b]pyridine plane [C-C-N-C torsion angles of 81.6 (4) and -77.2 (4)°] and point in the same direction. The planes through the atoms forming each allyl group are nearly perpendicular to the imidazo[4,5-b]pyridin-2-one system, as indicated by the dihedral angles between t ...[more]

PMID: 22091021

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