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6-Chloro-N-methyl-N-phenyl-pyrimidine-4,5-diamine.

ABSTRACT: In the title compound, C(11)H(11)ClN(4), the dihedral angle between the aromatic rings is 66.47?(8)°. In the crystal, mol-ecules are linked by N-H?N hydrogen bonds, generating C(5) chains propagating in [010]. Slipped aromatic ?-? stacking between centrosymmetrically related pairs of pyrim-idine rings also occurs [centroid-centroid separation = 3.7634?(12)Å and slippage = 1.715?Å].

SUBMITTER: Shi F

PROVIDER: S-EPMC3213532 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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6-Chloro-N-methyl-N-phenyl-pyrimidine-4,5-diamine.

Shi Fuqiang F Zhu Li-Hong LH Zhang Long L Li Ya-Feng YF

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

In the title compound, C(11)H(11)ClN(4), the dihedral angle between the aromatic rings is 66.47 (8)°. In the crystal, mol-ecules are linked by N-H⋯N hydrogen bonds, generating C(5) chains propagating in [010]. Slipped aromatic π-π stacking between centrosymmetrically related pairs of pyrim-idine rings also occurs [centroid-centroid separation = 3.7634 (12)Å and slippage = 1.715 Å]. ...[more]

PMID: 22091109

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