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2,4,5-Tris(biphenyl-2-yl)-1-bromo-benzene.

ABSTRACT: In the title compound, C(42)H(29)Br, the dihedral angles between the central benzene ring and the three attached benzene rings are very similar, lying in the range 52.65?(6)-57.20?(7)°. Of the dihedral angles between the rings of the o-biphenyl substituents, two are similar [46.34?(7) and 47.35?(7)°], while the other differs significantly [64.17?(7)°]. In the crystal, mol-ecules are linked into centrosymmetric dimers by two weak C-H?? inter-actions.

SUBMITTER: Rodrigues AS

PROVIDER: S-EPMC3213533 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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2,4,5-Tris(biphenyl-2-yl)-1-bromo-benzene.

Rodrigues Ana S M C AS Gomes Ligia R LR Santos Luís M N B F LM Low John Nicolson JN

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

In the title compound, C(42)H(29)Br, the dihedral angles between the central benzene ring and the three attached benzene rings are very similar, lying in the range 52.65 (6)-57.20 (7)°. Of the dihedral angles between the rings of the o-biphenyl substituents, two are similar [46.34 (7) and 47.35 (7)°], while the other differs significantly [64.17 (7)°]. In the crystal, mol-ecules are linked into centrosymmetric dimers by two weak C-H⋯π inter-actions. ...[more]

PMID: 22091110

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