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6-Bromo-1-methyl-4-[2-(4-methyl-benzyl-idene)hydrazinyl-idene]-3H-2?,1-benzothia-zine-2,2-dione.

ABSTRACT: In the title compound, C(17)H(16)BrN(3)O(2)S, the two fused rings are twisted by a dihedral angle of 6.61?(15)°. The thia-zine ring adopts a sofa conformation. The toluene ring is oriented at dihedral angles of 15.5?(2) and 20.6?(2)° with respect to the bromo-benzene and thia-zine rings, respectively. The benzyl-idene system is approximately planar [r.m.s. deviation = 0.0388?Å]. In the cyrstal, weak inter-molecular C-H?O hydrogen bonds connects the mol-ecules into a chain along the b axis.

SUBMITTER: Shafiq M

PROVIDER: S-EPMC3213534 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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6-Bromo-1-methyl-4-[2-(4-methyl-benzyl-idene)hydrazinyl-idene]-3H-2λ,1-benzothia-zine-2,2-dione.

Shafiq Muhammad M Khan Islam Ullah IU Zia-Ur-Rehman Muhammad M Arshad Muhammad Nadeem MN Asiri Abdullah M AM

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

In the title compound, C(17)H(16)BrN(3)O(2)S, the two fused rings are twisted by a dihedral angle of 6.61 (15)°. The thia-zine ring adopts a sofa conformation. The toluene ring is oriented at dihedral angles of 15.5 (2) and 20.6 (2)° with respect to the bromo-benzene and thia-zine rings, respectively. The benzyl-idene system is approximately planar [r.m.s. deviation = 0.0388 Å]. In the cyrstal, weak inter-molecular C-H⋯O hydrogen bonds connects the mol-ecules into a chain along the b axis. ...[more]

PMID: 22091111

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