Ontology highlight
ABSTRACT:
SUBMITTER: Saouma CT
PROVIDER: S-EPMC3215824 | biostudies-literature | 2011 Nov
REPOSITORIES: biostudies-literature
Saouma Caroline T CT Moore Curtis E CE Rheingold Arnold L AL Peters Jonas C JC
Inorganic chemistry 20111017 22
A family of iron(II) complexes that coordinate dinitrogen, diazene, hydrazine, and ammonia are presented. This series of complexes is unusual in that the complexes within it feature a common auxiliary ligand set and differ only by virtue of the nitrogenous N(x)H(y) ligand that occupies the sixth binding site. The ability of an iron center to bind N(2), N(2)H(2), N(2)H(4), and NH(3) is important to establish in the context of evaluating catalytic N(2) reduction schemes that invoke these nitrogeno ...[more]