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Short and efficient synthetic route to methyl ?-trioxacarcinoside B and anomerically activated derivatives.


ABSTRACT: A 9-step synthetic route to the complex carbohydrate methyl ?-trioxacarcinoside B from 2-acetylfuran is described. Anomerically activated forms, including 1-phenylthio, 1-O-(4'-pentenyl), 1-fluoro, and 1-O-acetyl derivatives are also prepared.

SUBMITTER: Magauer T 

PROVIDER: S-EPMC3216050 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Short and efficient synthetic route to methyl α-trioxacarcinoside B and anomerically activated derivatives.

Magauer Thomas T   Myers Andrew G AG  

Organic letters 20110929 20


A 9-step synthetic route to the complex carbohydrate methyl α-trioxacarcinoside B from 2-acetylfuran is described. Anomerically activated forms, including 1-phenylthio, 1-O-(4'-pentenyl), 1-fluoro, and 1-O-acetyl derivatives are also prepared. ...[more]

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