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[1,1'-Bis(diphenyl-phosphan-yl)cobalto-cenium]carbonyl-chloridohydrido(triphenyl-phosphane)ruthenium(II) hexa-fluoridophosphate dichloro-methane disolvate.


ABSTRACT: In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1'-bis-(diphenyl-phosphan-yl)cobaltocenium ligand and a triphenyl-phosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octa-hedral geometry. In the cobaltocenium unit, the two cyclo-penta-dienyl rings are almost parallel, making a dihedral angle of 1.2?(3)°. The F atoms of the hexa-fluoridophosphate anion are disordered over two sets of sites, with an occupancy ratio of 0.849?(11):0.151?(11). Intra-molecular C-H?Cl hydrogen bonds occur in the complex cation. The complex cations, hexa-fluoridophosphate anions and dichloro-methane solvent mol-ecules are linked by inter-molecular C-H?F hydrogen bonds.

SUBMITTER: Hou JG 

PROVIDER: S-EPMC3238603 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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[1,1'-Bis(diphenyl-phosphan-yl)cobalto-cenium]carbonyl-chloridohydrido(triphenyl-phosphane)ruthenium(II) hexa-fluoridophosphate dichloro-methane disolvate.

Hou Jian-Guo JG  

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12


In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1'-bis-(diphenyl-phosphan-yl)cobaltocenium ligand and a triphenyl-phosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octa-hedral geometry. In the cobaltocenium unit, the two cyclo-penta-dienyl rings are almost parallel, making a dihedral angle of 1.2 (3)°. The F atoms of the hexa-fluoridophosphate anion are disordered over  ...[more]

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