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Catena-Poly[[[triaqua-copper(II)]-?-2,2'-bipyridine-3,3'-dicarboxyl-ato-?N,N':O] monohydrate].

ABSTRACT: The title compound, {[Cu(C(12)H(6)N(2)O(4))(H(2)O)(3)]·H(2)O}(n), was synthesized under hydro-thermal conditions. The Cu(2+) ion is six-coordinated by three water O atoms, and two N atoms and one O atom of the 2,2'-bipyridine-3,3'-dicarboxyl-ate bridging ligand in a sligthly distorted octa-hedral environment. The 2,2-bipyridine-3,3'-dicarboxyl-ate bridges link the Cu(2+) ions into chains along the b-axis direction. These chains are further linked by O-H?O hydrogen bonds involving the water solvent mol-ecules, forming a three-dimensional framework.

SUBMITTER: Wu Q 

PROVIDER: S-EPMC3238631 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[[triaqua-copper(II)]-μ-2,2'-bipyridine-3,3'-dicarboxyl-ato-κN,N':O] monohydrate].

Wu Qihui Q   Wang Fuxiang F   Jiang Nanqing N   Cao Li L   Pan Qinhe Q  

Acta crystallographica. Section E, Structure reports online 20111109 Pt 12

The title compound, {[Cu(C(12)H(6)N(2)O(4))(H(2)O)(3)]·H(2)O}(n), was synthesized under hydro-thermal conditions. The Cu(2+) ion is six-coordinated by three water O atoms, and two N atoms and one O atom of the 2,2'-bipyridine-3,3'-dicarboxyl-ate bridging ligand in a sligthly distorted octa-hedral environment. The 2,2-bipyridine-3,3'-dicarboxyl-ate bridges link the Cu(2+) ions into chains along the b-axis direction. These chains are further linked by O-H⋯O hydrogen bonds involving the water solve  ...[more]

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