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Catena-Poly[[(1,10-phenanthroline-?N,N')zinc]-?-4-sulfonato-benzo-triazolido-?N,O:N].

ABSTRACT: In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonato-benzotriazolide dianions, two N atoms from a 1,10-phenanthroline mol-ecule and a sulfonate O atom from a 4-sulfonato-benzotriazolide anion, displaying a distorted ZnN(4)O trigonal-bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelating coordinating mode and the 4-sulfonato-benzotriazolide ions act as ?(2)-bridges, linking different Zn(2+) cations into a chain along the b axis. The crystal structure is consolidated by C-H?O hydrogen-bonding inter-actions.

SUBMITTER: Cheng XC

PROVIDER: S-EPMC3238664 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[(1,10-phenanthroline-κN,N')zinc]-μ-4-sulfonato-benzo-triazolido-κN,O:N].

Cheng Xiao-Chun XC

Acta crystallographica. Section E, Structure reports online 20111112 Pt 12

In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonato-benzotriazolide dianions, two N atoms from a 1,10-phenanthroline mol-ecule and a sulfonate O atom from a 4-sulfonato-benzotriazolide anion, displaying a distorted ZnN(4)O trigonal-bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelating coordinating mode and the 4-sulfonato-benzotriazolide ions act as μ(2)-bridges, linking different Zn( ...[more]

PMID: 22199555

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catena-Poly[[(1,10-phenanthroline)zinc]-?-2,2'-oxydibenzoato].

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| S-EPMC3212257 | biostudies-other

catena-Poly[[[diaqua-(1,10-phenanthroline-?(2)N,N')zinc]-?-4-hy-droxy-3-sulfonato-benzoato-?(2)O(3):O(1)] sesquihydrate].

Project description:The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion. It is also coordinated by two water mol-ecules in an overall octa-hedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O-H?O hydrogen bonds into a three-dimensional network.

| S-EPMC3379067 | biostudies-literature

catena-Poly[[(1,10-phenanthroline)cobalt]-?-2,4'-oxydibenzoato].

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| S-EPMC3414136 | biostudies-literature

catena-Poly[[(1,10-phenanthroline)zinc]-μ-3-[3-(carboxyl-atometh-oxy)phen-yl]acrylato].

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catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato].

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catena-Poly[[bis-[aqua-(1,10-phenanthroline)lead(II)]-bis-(μ₃-2-hy-droxy-5-sulfonato-benzoato)] acetic acid monosolvate].

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catena-Poly[[[aqua-(pyrazino-[2,3-f][1,10]phenanthroline-?N,N)zinc(II)]-?-penta-nedioato] monohydrate].

Project description:In the title compound, {[Zn(C(5)H(6)O(4))(C(14)H(8)N(4))(H(2)O)]·H(2)O}(n), the Zn(2+) ion is coordinated by an N,N'-bidentate pyrazino-[2,3-f][1,10]phenanthroline (pyphen) ligand, a water molecule and a monodentate glutarate (glu) dianion. A symmetry-generated O:O'-bidentate glu dianion completes a distorted cis-ZnN(2)O(4) octa-hedral coordination geometry for the metal ion. The bridging glu species generates [110] polymeric chains in the crystal. O-H?O hydrogen bonds involving both the coordinated and uncoordinated water mol-ecules help to consolidate the structure and neighbouring pyphen units inter-act through numerous aromatic ?-? inter-actions [minimum centroid-centroid separation = 3.654?(3)?Å], resulting in a two-dimensional network.

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catena-Poly[[[(1,10-phenanthroline)copper(I)]-?-cyanido] ethanol hemisolvate].

Project description:In the title coordination polymer, {[Cu(CN)(C(12)H(10)N(2))]·0.5C(2)H(5)OH}(n), there are two Cu(I) ions, two 1,10-phenanthroline (phen) ligands and two cyanide ions in the asymmetric unit along with a highly disordered ethanol solvent mol-ecule, which was modelled as being disordered over two sets of sites in a 0.829?(7):0.171?(7) ratio. The orientation/ordering of the C and N atoms of the cyanide ions could not be determined in the present refinement and they were modelled as being statistically disordered. Both copper ions are coordinated by an N,N'-bidentate phen ligand and two cyanide ligands, generating distorted tetra-hedral CuN(2)Q(2) (Q = C or N) tetra-hedra. The ?-cyanide ligands link the metal ions, forming a zigzag chain propagating in [001]. The chains are cross-linked by numerous aromatic ?-? stacking contacts between adjacent phen rings [minimum centroid-centroid separation = 3.620?(3)?Å].

| S-EPMC3011795 | biostudies-literature

catena-Poly[[(1,10-phenanthroline-?N,N')copper(I)]-?(2)-iodido].

Project description:The solvothermal reaction of copper(I) iodide and 1,10-phenanthroline (phen) in ethanol yielded the title polymeric compound, [CuI(C(12)H(8)N(2))](n). The asymmmetric unit comprises one Cu(+) cation, one I(-) anion and one phen ligand. Each Cu(+) cation is in a distorted tetrahedral coordination by two iodide anions and two N atoms from a bidentate chelating phen ligand. The Cu(+) cations are bridged through the iodide anions, leading to a zigzag chain structure extending parallel to [100]. There are ?-? inter-actions among adjacent phen ligands of one chain [centroid-centroid distance = 3.693?(3)?Å].

| S-EPMC3009332 | biostudies-literature

Poly[[(1,10-phenanthroline)(?-l-tartrato)zinc] hexa-hydrate].

Project description:The title compouand {[Zn(C(4)H(4)O(6))(C(12)H(8)N(2))]·6H(2)O}(n), has a linear chain structure parallel to [100] with Zn(C(4)H(4)O(6))(C(12)H(8)N(2)) repeat units; the asymmetric unit consists of one Zn(2+) cation, one l-tartrate dianion, one 1,10-phenanthroline and six free water mol-ecules. The Zn atom is in a distorted octa-hedral ZnN(2)O(4) coordination environment. The crystal structure is stabilized by O-H?O hydrogen bonds and ?-? stacking of the phenanthroline units [centroid-centroid distances in the range 3.552?(2)-3.625?(2)Å] occurs between the chains. The title compound is isotypic with the Cu and Mn analogues.

| S-EPMC3152042 | biostudies-literature

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