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[1,5-Bis(2-meth-oxy-phen-yl)thio-carbazo-nato-?N,S]phenyl-mercury(II).

ABSTRACT: The title compound, [Hg(C(6)H(5))(C(15)H(15)N(4)O(2)S)], shows the metal-phenyl moiety coordinated out of plane with the thio-carbazo-nate ligand by 43.84?(6)°. Important geometrical parameters include Hg-S = 2.3653?(10)?Å, Hg-C = 2.058?(4)?Å and S-Hg-C = 179.06?(11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg-N = 2.725?(3)?Å]. S?Hg inter-actions[3.2928?(10)?Å] form chains along [001], stabilizing the crystal structure.

SUBMITTER: von Eschwege K

PROVIDER: S-EPMC3238710 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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[1,5-Bis(2-meth-oxy-phen-yl)thio-carbazo-nato-κN,S]phenyl-mercury(II).

von Eschwege Karel K Muller Fabian F Muller Alfred A

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12

The title compound, [Hg(C(6)H(5))(C(15)H(15)N(4)O(2)S)], shows the metal-phenyl moiety coordinated out of plane with the thio-carbazo-nate ligand by 43.84 (6)°. Important geometrical parameters include Hg-S = 2.3653 (10) Å, Hg-C = 2.058 (4) Å and S-Hg-C = 179.06 (11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg-N = 2.725 (3) Å]. S⋯Hg inter-actions[3.2928 (10) Å] form chains along [001], stabilizing the crystal structure. ...[more]

PMID: 22199587

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