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4,5-Dihydro-3a,5a-diazo-niapyrene triiodidocuprate(I).

ABSTRACT: In the dianion of the title salt, (C(14)H(12)N(2))[CuI(3)], the Cu(I) atom is coordinated by three I(-) ions that define a nearly trigonal-planar geometry; the Cu(I) atom lies 0.1407?(6)?Å out of the plane. With the exception of the methyl-ene C atoms, the dication is essentially planar (r.m.s deviation = 0.067?Å). The most significant inter-action between the ions is a C-H?I contact.

SUBMITTER: Wu D

PROVIDER: S-EPMC3238737 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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4,5-Dihydro-3a,5a-diazo-niapyrene triiodidocuprate(I).

Wu Di D Hao Peng-Chao PC Niu Yun-Yin YY Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20111125 Pt 12

In the dianion of the title salt, (C(14)H(12)N(2))[CuI(3)], the Cu(I) atom is coordinated by three I(-) ions that define a nearly trigonal-planar geometry; the Cu(I) atom lies 0.1407 (6) Å out of the plane. With the exception of the methyl-ene C atoms, the dication is essentially planar (r.m.s deviation = 0.067 Å). The most significant inter-action between the ions is a C-H⋯I contact. ...[more]

PMID: 22199614

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