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(1,2,3,4-Tetra-hydro-isoquinoline-2-carbo-dithio-ato-?S,S')(thio-cyanato-?N)(tri-phenyl-phosphane)nickel(II).

ABSTRACT: The Ni(II) atom in the mononuclear title compound, [Ni(C(10)H(10)NS(2))(NCS)(C(18)H(15)P)], exists within a S(2)PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni-S bond lengths support the less effective trans effect of SCN(-) over PPh(3).

SUBMITTER: Valarmathi P

PROVIDER: S-EPMC3238766 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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(1,2,3,4-Tetra-hydro-isoquinoline-2-carbo-dithio-ato-κS,S')(thio-cyanato-κN)(tri-phenyl-phosphane)nickel(II).

Valarmathi P P Thirumaran S S Selvanayagam S S

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

The Ni(II) atom in the mononuclear title compound, [Ni(C(10)H(10)NS(2))(NCS)(C(18)H(15)P)], exists within a S(2)PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni-S bond lengths support the less effective trans effect of SCN(-) over PPh(3). ...[more]

PMID: 22199643

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