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(S)-Methyl 3-(3,4-dimeth-oxy-phen-yl)-2-[2-(diphenyl-phosphan-yl)benzamido]-propano-ate.

ABSTRACT: Mol-ecules of the title compound, C(31)H(30)NO(5)P, show a sttagered conformation about the C-C bond joining the dimeth-oxy-benzene group to the chiral centre, with the dimeth-oxy-benzene ring gauche to the amide group and anti to the ester group. In the crystal, weak inter-molecular N-H⋯O and C-H⋯O hydrogen bonds form layers parallel to (110).

SUBMITTER: Naicker T

PROVIDER: S-EPMC3238941 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(S)-Methyl 2-benzamido-3-(3,4-dimeth-oxy-phen-yl)propano-ate.

Project description:The dimethoxypbenzene ring in the title compound, C(19)H(21)NO(5), is gauche to the amide group and anti to the ester group. The chirality was confirmed to be S from two-dimensional NMR spectroscopy. In the crystal, N-H?O and C-H?O hydrogen bonds and several short-contact inter-actions (2.07-3.45?Å) create chains parallel to [110]. The phenyl ring is disordered over two orientations in a 0.54?(2):0.46?(2) ratio.

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(R*)-Methyl 2-(2,6-dimeth-oxy-3,5-di-nitro-benzamido)-propano-ate.

Project description:In the title mol-ecule, C(13)H(15)N(3)O(9), the nitro groups are tilted with respect to the benzene mean plane by 22.8?(3) and 31.6?(3)°. The meth-oxy groups are in a cis orientation relative to the ring. In the crystal, mol-ecules are linked by strong N-H?O hydrogen bonds into C(3) chains along [100].

| S-EPMC3414311 | biostudies-literature

Methyl 2-{N-[2-(2,4-dichloro-phen-oxy)acet-yl]-4-[(4,6-dimeth-oxy-pyrimidin-2-yl)-oxy]anilino}propano-ate.

Project description:In the title mol-ecule, C(24)H(23)Cl(2)N(3)O(7), the central benzene ring forms dihedral angles of 65.71?(1) and 44.42?(1)° with the pyrimidine ring and the terminal benzene ring, respectively. In the crystal, molecules are linked via C-H?O hydrogen bonds.

| S-EPMC3393314 | biostudies-literature

(3,4-Dimeth-oxy-phen-yl)(4-fluoro-phen-yl)methanone.

Project description:In the title compound, C(15)H(13)FO(3), the dihedral angle between the two aromatic rings is 52.78?(8)°. In the crystal, inter-molecular C-H?O hydrogen bonds link mol-ecules into chains running parallel to the c axis.

| S-EPMC3006767 | biostudies-literature

2-(3,4-Dimeth-oxy-phen-yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole.

Project description:In the title compound, C(26)H(24)N(2)O(2), the planar 1H-imidazole ring makes dihedral angles of 35.78?(4), 26.35?(5) and 69.75?(5)°, respectively, with the dimeth-oxy-phenyl ring and the phenyl rings in the 4- and 5-positions. In the crystal, C-H?O hydrogen bonds connect neighbouring mol-ecules, forming infinite chains running along the b axis. Furthermore, the crystal structure exhibits a C-H-?? inter-action between a methyl H atom and a phenyl ring from an adjacent mol-ecule.

| S-EPMC3470344 | biostudies-literature

2-(3,4-Dimeth-oxy-phen-yl)-1H-benzimidazole.

Project description:In title compound, C(15)H(14)N(2)O(2), the dihedral angle between the 3,4-dimeth-oxy-phenyl group and the benzimidazole system is 26.47 (6)°. In the crystal, neighbouring mol-ecules are linked by N-H⋯N hydrogen bonds into C(4) chains propagating along the c-axis direction. The crystal structure also features weak C-H⋯O inter-actions.

| S-EPMC3238911 | biostudies-literature

(E)-3-(2,4-Dimeth-oxy-phen-yl)-1-(3,4-dimeth-oxy-phen-yl)prop-2-en-1-one.

Project description:The title compound, C(19)H(20)O(5), is approximately planar; the dihedral angle between the benzene rings is 3.82?(8)°, and the central propenone C(=O)-C=C plane makes dihedral angles of 1.95?(10) and 3.17?(11)° with the two benzene rings. In the crystal structure, intra- and inter-molecular C-H?O hydrogen bonds are observed.

| S-EPMC3009186 | biostudies-literature

(3,4-Dimeth-oxy-phen-yl)[2-(thio-phen-2-ylcarbon-yl)phen-yl]methanone.

Project description:In the title compound, C(20)H(16)O(4)S, the thiophene ring makes dihedral angles of 72.9?(2) and 60.5?(2)°, respectively, with the dimethoxy benzene and phenyl rings. In the crystal, C-H?O hydrogen bonds link the mol-ecules into a C(9) chain along the b axis. The S and C atoms of the thio-phene ring are disordered over two sets of sites [site occupancies = 0.675?(3) and 0.325?(3)]. A short inter-molecular S?O contact [3.084?(2)?Å] is observed in the crystal structure, which also features C-H?? inter-actions.

| S-EPMC3470204 | biostudies-literature

2-(2-Chloro-phen-yl)-3-(3,4-dimeth-oxy-phen-yl)quinoxaline.

Project description:The title compound, C(22)H(17)ClN(2)O(2), was synthesized by the condensation reaction between 1,2-phenyl-enediamine and 2-chloro-3',4'-dimeth-oxy-benzil in boiling acetic acid. The chloro-phenyl and dimeth-oxy-phenyl rings make dihedral angles of 78.45 (5) and 35.60 (4)°, respectively, with the quinoxaline unit.

| S-EPMC3007581 | biostudies-literature

1-(3,4-Dimeth-oxy-phen-yl)propan-1-one.

Project description:The title compound, C(11)H(14)O(3), was isolated from the stems of Trigonostemon xyphophylloides, which belongs to Trigonostemon genus of Euphorbiaceae. The plants in this genus were used in folk medicine, such as for the treatment of diseases caused by viruses and fungi. The limited investigation of the chemistry of this plant prompted an examination of constituents of its twigs, from which the title compound was isolated. The mol-ecule is approximately planar with an r.m.s. deviation of 0.1237Å. In the crystal, inter-molecular C-H?O hydrogen bonds connect the mol-ecules into a two-dimensional network structure with an R(2) (2)(12) graph-set motif.

| S-EPMC3201510 | biostudies-literature

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