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(Z)-N-{3-[(2-Chloro-1,3-thia-zol-5-yl)meth-yl]-1,3-thia-zolidin-2-yl-idene}cyanamide.

ABSTRACT: In the title compound, C(8)H(7)ClN(4)S(2), the thia-zole ring is essentially planar [r.m.s. deviation = 0.0011 (2) Å] and conformation of the thia-zolidine ring is twisted on the C-C bond. The C=N bond has a Z configuration.

SUBMITTER: Li YM

PROVIDER: S-EPMC3238956 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(Z)-N-{3-[(6-Chloro-pyridin-3-yl)meth-yl]-1,3-thia-zolidin-2-yl-idene}cyanamide.

Project description:The asymmetric unit of the title compound, C(10)H(9)ClN(4)S, common name thia-cloprid, comprises two mol-ecules. In both mol-ecules, the thia-zolidine rings are almost planar (with r.m.s. deviations of 0.016 and 0.065?Å) and form dihedral angles of 73.36?(6) and 70.25?(8)° with the 2-chloro-pyridine rings. In the crystal, inter-molecular C-H?N hydrogen bonds links the mol-ecules into chains propagating in [[Formula: see text]01].

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{3-[(2-Chloro-1,3-thia-zol-4-yl)meth-yl]-1,3-thia-zolidin-2-yl-idene-amino}-formonitrile.

Project description:In the title compound, C(8)H(7)ClN(4)S(2), the dihedral angle between the thia-zolidine ring (r.m.s. deviation = 0.028?Å) and the thia-zole ring (r.m.s. deviation = 0.004?Å) is 74.74?(6)°. The formonitrile group is almost coplanar with the attached ring [C-N-C-N torsion angle = 167?(2)°.

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(Z)-N-(3-Nicotinoyl-1,3-thia-zolidin-2-yl-idene)cyanamide.

Project description:In the title compound, C(10)H(8)N(4)OS, the dihedral angle between the pyridine and thia-zolidine rings is 52.5?(5)°. Inter-molecular C-H?N inter-actions help to stabilize the crystal structure.

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(Z)-N-[3-(4-Bromo-benzo-yl)-1,3-thia-zolidin-2-yl-idene]cyanamide.

Project description:In the title compound, C(11)H(8)BrN(3)OS, the dihedral angle between the benzene and thia-zolidine rings is 63.4?(2)°. Inter-molecular C-H?N inter-actions help to stabilize the crystal structure.

| S-EPMC3011547 | biostudies-literature

N-[(Z)-3-(4-Chloro-benzo-yl)-1,3-thia-zolidin-2-yl-idene]cyanamide.

Project description:The title compound, C(11)H(8)ClN(3)OS, was prepared by the reaction of N-cyano-imino-thia-zolidine, 2-amino-ethanethiol and triethyl-amine at 350?K. The dihedral angle between the two rings is 62.5?(8)°.

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(Z)-N-{3-[1-(4-Chloro-phen-yl)eth-yl]thia-zolidin-2-yl-idene}cyanamide.

Project description:The title compound, C(12)H(12)ClN(3)S, features a thia-zolyl ring having an envelope conformation with the -CH(2)- group bonded to the S atom forming the flap. The C=N double bond has a Z configuration. The crystal structure shows inter-molecular C-H?S hydrogen bonds.

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2-Isopropyl-2-(6-meth-oxy-1,3-benzo-thia-zol-2-yl)-5,5-dimethyl-1,3-thia-zolidin-4-one.

Project description:The title compound, C16H20N2O2S2, crystallizes with two enanti-omers (A and B) in the asymmetric unit. The most noticeable difference between these two mol-ecules is the relative orientation of the benzo-thia-zole rings, with S-C-C-S torsion angles of -19.4?(2) (mol-ecule A) and 100.6?(1)° (mol-ecule B). The amide structure of the thia-zolidinone rings leads to inter-molecular hydrogen-bonded dimers of the R and S enanti-omers.

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{2-[(1,3-Benzo-thia-zol-2-yl)meth-oxy]-5-chloro-phen-yl}(4-chloro-phen-yl)methan-one.

Project description:In the title compound, C21H13Cl2NO2S, the benzo-thia-zole ring makes dihedral angles of 0.94?(1) and 70.65?(5)° with the 4-chloro-phenyl-methanone unit and the 5-chloro-phenyl ring, respectively. The dihedral angle between the 4-chloro-phenyl-methanone unit and the 5-chloro-phenyl ring is 66.20?(5)°. The crystal structure consists of dimeric units generated by C-H?N hydrogen bonds, further linked by C-H?O and C-H?? inter-actions, leading to a three-dimensional network.

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3-[(2-Chloro-1,3-thia-zol-5-yl)meth-yl]-5-methyl-1,3,5-oxadiazinan-4-one.

Project description:In the title compound, C(8)H(10)ClN(3)O(2)S, the oxadiazinane ring is in a sofa conformation with the ring O atom deviating from the best plane of the remaining five atoms by 0.636?(2)?Å. A short intra-molecular C-S?O=C contact [S?O 3.122?(2)?Å, C-S?O 80.0?(2)°] is observed between the two mol-ecular fragments bridged by the methyl-ene group. In the crystal, C-H?O hydrogen bonds link mol-ecules, forming chains along the b axis.

| S-EPMC3515215 | biostudies-literature

(Z)-2-(1,3-Thia-zolidin-2-yl-idene)cyan-amide.

Project description:In the title compound, C(4)H(5)N(3)S, the tdihydrothiazole ring is almost planar, the maximum and minimum deviations being 0.188?(2)?Å and 0.042?(3)?Å, respectively. The crystal structure involves intermolecular N-H?N hydrogen bonds.

| S-EPMC3007512 | biostudies-literature

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