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(2R,3R)-1-(4-Chloro-phen-yl)-2-[(S)-2-nitro-1-phenyl-eth-yl]-3-phenyl-pentan-1-one.

ABSTRACT: The title compound, C(25)H(24)ClNO(3), has three contiguous chiral centres. The absolute structure was determined by anomalous dispersion. The chloro-benzene ring is inclined to the two phenyl rings by 14.98?(9) and 59.05?(9)°. The two phenyl rings are inclined to one another by 49.51?(10)°. In the crystal, neighbouring mol-ecules are linked via C-H?O hydrogen bonds, forming chains propagating along [010]. There is also a C-H?? inter-action present that leads to the formation of a three-dimensional network.

SUBMITTER: Duo DL

PROVIDER: S-EPMC3239119 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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(2R,3R)-1-(4-Chloro-phen-yl)-2-[(S)-2-nitro-1-phenyl-eth-yl]-3-phenyl-pentan-1-one.

Duo De-Long DL Ni Cheng-Yan CY Wen Qing-Song QS

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

The title compound, C(25)H(24)ClNO(3), has three contiguous chiral centres. The absolute structure was determined by anomalous dispersion. The chloro-benzene ring is inclined to the two phenyl rings by 14.98 (9) and 59.05 (9)°. The two phenyl rings are inclined to one another by 49.51 (10)°. In the crystal, neighbouring mol-ecules are linked via C-H⋯O hydrogen bonds, forming chains propagating along [010]. There is also a C-H⋯π inter-action present that leads to the formation of a three-dimensio ...[more]

PMID: 22199967

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