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(SP-4-2)-Chlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]benzyl-amine-κP,N}(meth-yl)palladium(II).

ABSTRACT: In the title Pd(II) complex, [Pd(CH(3))Cl(C(26)H(22)NP)], the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand.

SUBMITTER: Chiririwa H

PROVIDER: S-EPMC3246930 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Chlorido[2-({[2-(diphenyl-phosphan-yl)-benzyl-idene]amino}-meth-yl)thio-phene-?N,P]methyl-palladium(II).

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Project description:The asymmetric unit of the title compound, [AuCl(C31H32NP)]·0.25CHCl3, contains two independent complex mol-ecules and half a chloro-form solvent mol-ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P-Au-Cl angles of 177.20?(4) and 178.54?(4)°.

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