Unknown

Dataset Information

0

μ-Oxido-bis-[bis-(phenanthroline-κN,N')(sulfato-κO)iron(III)] octa-hydrate.

ABSTRACT: The title complex, [Fe(2)O(SO(4))(2)(C(12)H(8)N(2))(4)]·8H(2)O, contains two unique Fe(III) cations, one oxide anion, four 1,10-phenanthroline (phen) ligands, two coordinated sulfate anions and eight lattice water mol-ecules. Each Fe(III) ion has an approximate octa-hedral geometry, coordinated by four N atoms from two phen mol-ecules, two O atoms from oxide and sulfate anions, respectively. The parallel phen mol-ecules form two-dimensional supermolecules through π-π stacking inter-actions [centroid-centroid distances = 3.684 (3), 3.711 (3), 3.790 (3), 3.847 (3), 3.746 (3), 3.732 (3) and 3.729 (3) Å]. This architecture is further stabilized by O-H⋯O hydrogen bonds involving the lattice water mol-ecules and sulfate O atoms.

SUBMITTER: Zhang J 

PROVIDER: S-EPMC3246986 | biostudies-literature |

REPOSITORIES: biostudies-literature

Json Xml

Similar Datasets

Unknown Hexa-μ(2)-acetato-κO:O'-(azido-κN)bis-(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate.
| S-EPMC3246918 | biostudies-literature
Unknown catena-Poly[[[tetra-kis-(4-methyl-pyridine-κN)copper(II)]-μ-sulfato-κO:O'] 4.393-hydrate].
| S-EPMC3051987 | biostudies-literature
Unknown Poly[[(1,10-phenanthroline-κN,N')zinc]-μ-2,5-bis-(all-yloxy)terephthalato-κO:O].
| S-EPMC3151955 | biostudies-literature
Unknown catena-Poly[[triaqua-(pyridine-κN)nickel(II)]-μ-sulfato-κO:O'].
| S-EPMC2971987 | biostudies-literature
Unknown Bis(μ-2,4-dihy-droxy-benzoato-κO:O')bis-[aqua-(2,4-dihy-droxy-benzoato-κO)(1,10-phenanthroline-κN,N')cadmium(II)].
| S-EPMC3006915 | biostudies-literature
Unknown Bis(μ-3-hydroxy-benzoato-κO,O':O)bis-[aqua-(3-hydroxy-benzoato-κO,O')(1,10-phenanthroline-κN,N')lead(II)] monohydrate.
| S-EPMC2915093 | biostudies-literature
Unknown Poly[[(μ-2,2'-bipyrimidine-κN,N:N,N)(μ-sulfato-κO:O')zinc(II)] monohydrate].
| S-EPMC2979934 | biostudies-literature
Unknown Tetra-kis(μ-phenoxy-acetato-κO:O')bis-[(1,10-phenanthroline-κN,N')manganese(II)] methanol hemisolvate.
| S-EPMC2915099 | biostudies-literature
Unknown catena-Poly[[(1,10-phenanthroline-κN,N')praseodymium(III)]-di-μ-phenoxy-acetato-κO:O'-[(1,10-phenanthroline-κN,N')praseodymium(III)]-di-μ-phenoxy-acetato-κO:O'-di-μ-phenoxy-acetato-κO,O':O;κO:O,O'].
| S-EPMC2960179 | biostudies-literature
Unknown Bis(μ-3-hy-droxy-benzoato)-κO,O:O;κO:O,O-bis-[(3-hy-droxy-benzoato-κO,O')(iso-nicotinamide-κN)cadmium] tetra-hydrate.
| S-EPMC3274919 | biostudies-literature