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4-Chloro-N-(3,4-dichloro-phen-yl)-2-methyl-benzene-sulfonamide.


ABSTRACT: In the title compound, C(13)H(10)Cl(3)NO(2)S, the N-C bond in the C-SO(2)-NH-C segment forms trans and gauche torsion angles with respect to the S=O bonds. Further, the N-H bond in the C-SO(2)-NH-C segment is anti to the meta-Cl atom in the anilino benzene ring and nearly syn with respect to the ortho-methyl group in the sulfonyl benzene ring. The C-SO(2)-NH-C torsion angle is -49.4?(2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 54.6?(1)°. In the crystal, mol-ecules are linked into chains along the c-axis direction by inter-molecular N-H?O hydrogen bonds.

SUBMITTER: Rodrigues VZ 

PROVIDER: S-EPMC3247351 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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4-Chloro-N-(3,4-dichloro-phen-yl)-2-methyl-benzene-sulfonamide.

Rodrigues Vinola Z VZ   Foro Sabine S   Gowda B Thimme BT  

Acta crystallographica. Section E, Structure reports online 20111012 Pt 11


In the title compound, C(13)H(10)Cl(3)NO(2)S, the N-C bond in the C-SO(2)-NH-C segment forms trans and gauche torsion angles with respect to the S=O bonds. Further, the N-H bond in the C-SO(2)-NH-C segment is anti to the meta-Cl atom in the anilino benzene ring and nearly syn with respect to the ortho-methyl group in the sulfonyl benzene ring. The C-SO(2)-NH-C torsion angle is -49.4 (2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 54.6 (1)°. In the crystal, mol-e  ...[more]

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