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2-[N-(3-Amino-4-nitro-phen-yl)carboximido-yl]phenol.

ABSTRACT: The title compound, C(13)H(11)N(3)O(3), is essentially planar (r.m.s. for the 19 non-H atoms = 0.031?Å), a conformation stabilized in part by intra-molecular O-H?N and N-H?O hydrogen bonds. The configuration about the imine bond [1.2919?(12)?Å] is E. The presence of N-H?O(nitro) hydrogen bonds leads to the formation of supra-molecular tapes in the crystal structure. These are connected into layers by ?-? inter-actions [centroid-centroid distance = 3.6046?(6)?Å] occurring between the hy-droxy- and amino-substituted benzene rings.

SUBMITTER: Shahverdizadeh GH

PROVIDER: S-EPMC3247370 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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2-[N-(3-Amino-4-nitro-phen-yl)carboximido-yl]phenol.

Shahverdizadeh Gholam Hossein GH Ng Seik Weng SW Tiekink Edward R T ER Mirtamizdoust Babak B

Acta crystallographica. Section E, Structure reports online 20111012 Pt 11

The title compound, C(13)H(11)N(3)O(3), is essentially planar (r.m.s. for the 19 non-H atoms = 0.031 Å), a conformation stabilized in part by intra-molecular O-H⋯N and N-H⋯O hydrogen bonds. The configuration about the imine bond [1.2919 (12) Å] is E. The presence of N-H⋯O(nitro) hydrogen bonds leads to the formation of supra-molecular tapes in the crystal structure. These are connected into layers by π-π inter-actions [centroid-centroid distance = 3.6046 (6) Å] occurring between the hy-droxy- an ...[more]

PMID: 22219988

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Crystal structure of 2-{[(5-nitro-thio-phen-2-yl)methyl-idene]amino}-phenol.

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