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Exo-10,11-Dibromo-tricyclo-[6.3.1.0]dodeca-2,4,6,9-tetra-ene.

ABSTRACT: The title compound, C(12)H(10)Br(2), is a bridged ring system based on a homobenzonorbornadiene framework. The exo configuration of one of the Br atoms was previously assigned via NMR correlations and has now been confirmed by the geometry of the solid-state structure. The compound features a Br-C-C-Br torsion angle of 66.68?(12)°, whereby the C atoms in the calculation are respectively sp(3)- and sp(2)-hybridized.

SUBMITTER: Johnson KR

PROVIDER: S-EPMC3247379 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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exo-10,11-Dibromo-tricyclo-[6.3.1.0]dodeca-2,4,6,9-tetra-ene.

Johnson Kevin R D KR Bender Christopher O CO Boeré René T RT

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

The title compound, C(12)H(10)Br(2), is a bridged ring system based on a homobenzonorbornadiene framework. The exo configuration of one of the Br atoms was previously assigned via NMR correlations and has now been confirmed by the geometry of the solid-state structure. The compound features a Br-C-C-Br torsion angle of 66.68 (12)°, whereby the C atoms in the calculation are respectively sp(3)- and sp(2)-hybridized. ...[more]

PMID: 22219997

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