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Opipramol dihydro-chloride.

ABSTRACT: THE TITLE COMPOUND (SYSTEMATIC NAME:4-{3-[2-aza-tricyclo-[9.4.0.0(3,8)]penta-deca-1(15),3,5,7,11,13-hexaen-2-yl]prop-yl}-1-(2-hy-droxy-eth-yl)piperazine-1,4-diium dichloride), C(23)H(31)N(3)O(+)·2Cl(-), is the dihydro-chloride of a piperazine derivative bearing a bulky 3-(5H-dibenz[b,f]azepin-5-yl)propyl substituent. Protonation took place on both N atoms of the piperazine unit. The diaza-cyclo-hexane ring adopts a chair conformation. N-H?Cl, O-H?Cl and C-H?Cl hydrogen bonding as well as C-H?O contacts connect the components into a three-dimensional network in the crystal. Two C-H?? contacts are also observed.

SUBMITTER: Betz R 

PROVIDER: S-EPMC3247396 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Opipramol dihydro-chloride.

Betz Richard R   Gerber Thomas T   Hosten Eric E   Siddaraju Budanoor P BP   Yathirajan Hemmige S HS  

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

<h4>The title compound (systematic name</h4>4-{3-[2-aza-tricyclo-[9.4.0.0(3,8)]penta-deca-1(15),3,5,7,11,13-hexaen-2-yl]prop-yl}-1-(2-hy-droxy-eth-yl)piperazine-1,4-diium dichloride), C(23)H(31)N(3)O(+)·2Cl(-), is the dihydro-chloride of a piperazine derivative bearing a bulky 3-(5H-dibenz[b,f]azepin-5-yl)propyl substituent. Protonation took place on both N atoms of the piperazine unit. The diaza-cyclo-hexane ring adopts a chair conformation. N-H⋯Cl, O-H⋯Cl and C-H⋯Cl hydrogen bonding as well as  ...[more]

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