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(E)-N'-(2-Chloro-benzyl-idene)-3,5-di-hydroxy-benzohydrazide dihydrate.

ABSTRACT: In the Schiff base mol-ecule of the title compound, C(14)H(11)ClN(2)O(3)·2H(2)O, the benzene rings form a dihedral angle of 20.6?(1)°. The water molecules of crystallization are involved in the formation of a three-dimensional hydrogen-bonding network via O-H?O and N-H?O hydrogen bonds.

SUBMITTER: Yuan L

PROVIDER: S-EPMC3247416 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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(E)-N'-(2-Chloro-benzyl-idene)-3,5-di-hydroxy-benzohydrazide dihydrate.

Yuan Ling L Nan Yi Y Li Jing-Yuan JY Huang Xiu-Lan XL

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

In the Schiff base mol-ecule of the title compound, C(14)H(11)ClN(2)O(3)·2H(2)O, the benzene rings form a dihedral angle of 20.6 (1)°. The water molecules of crystallization are involved in the formation of a three-dimensional hydrogen-bonding network via O-H⋯O and N-H⋯O hydrogen bonds. ...[more]

PMID: 22220034

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Project description:The asymmetric unit of the title compound, C(14)H(11)ClN(2)O(2)·H(2)O, contains a Schiff base mol-ecule and a water mol-ecule of crystallization. The dihedral angle between the two aromatic rings is 27.3 (4)°. In the crystal structure, mol-ecules are linked into a two-dimensional network parallel to the bc plane by inter-molecular O-H⋯O and N-H⋯O hydrogen bonds involving the water mol-ecules.

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