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4-(o-Tol-yl)piperazin-1-ium chloride.

ABSTRACT: In the title mol-ecular salt, C(11)H(17)N(2) (+)·Cl(-), the piperazin-1-ium ring adopts a chair conformation with the aromatic ring in a pseudo-equatorial orientation. The dihedral angle between the benzene ring and the mean plane of the piperazin-1-ium ring is 51.22?(6)°. In the crystal, N-H?Cl hydrogen bonds link the mol-ecules into chains propagating in [100]. Weak C-H?? inter-actions also ocur.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3247500 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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4-(o-Tol-yl)piperazin-1-ium chloride.

Fun Hoong-Kun HK Asik Safra Izuani Jama SI Chandrakantha B B Isloor Arun M AM Shetty Prakash P

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title mol-ecular salt, C(11)H(17)N(2) (+)·Cl(-), the piperazin-1-ium ring adopts a chair conformation with the aromatic ring in a pseudo-equatorial orientation. The dihedral angle between the benzene ring and the mean plane of the piperazin-1-ium ring is 51.22 (6)°. In the crystal, N-H⋯Cl hydrogen bonds link the mol-ecules into chains propagating in [100]. Weak C-H⋯π inter-actions also ocur. ...[more]

PMID: 22220118

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