Unknown

Dataset Information

0

(4R,4aS,4bS,7R,10aR)-4-Hy-droxy-4a,7-dimethyl-2-(propan-2-yl)-1,4,4a,4b,5,6,7,8,10,10a-deca-hydro-phenanthren-1-one.


ABSTRACT: In the title compound, C(19)H(28)O(2), the A ring adopts a chair conformation, and each of the B and C rings adopts a distorted half-chair conformation with the methine C atom in the CH(2)C(H)C(=O) residue, common to both rings, lying 0.6397?(19) and 0.6328?(18)?Å out of the approximate plane defined by the remaining five C atoms (r.m.s. deviations = 0.0791 and 0.0901?Å for rings B and C, respectively). Helical supra-molecular chains along the a axis mediated by hy-droxy-carbonyl O-H?O hydrogen bonds feature in the crystal packing.

SUBMITTER: Caracelli I 

PROVIDER: S-EPMC3247520 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

altmetric image

Publications

(4R,4aS,4bS,7R,10aR)-4-Hy-droxy-4a,7-dimethyl-2-(propan-2-yl)-1,4,4a,4b,5,6,7,8,10,10a-deca-hydro-phenanthren-1-one.

Caracelli Ignez I   Zukerman-Schpector Julio J   Machado André T Lousada AT   Brocksom Timothy J TJ   Ferreira M Lúcia ML   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11


In the title compound, C(19)H(28)O(2), the A ring adopts a chair conformation, and each of the B and C rings adopts a distorted half-chair conformation with the methine C atom in the CH(2)C(H)C(=O) residue, common to both rings, lying 0.6397 (19) and 0.6328 (18) Å out of the approximate plane defined by the remaining five C atoms (r.m.s. deviations = 0.0791 and 0.0901 Å for rings B and C, respectively). Helical supra-molecular chains along the a axis mediated by hy-droxy-carbonyl O-H⋯O hydrogen  ...[more]

Similar Datasets

| S-EPMC3238985 | biostudies-literature
| S-EPMC3238859 | biostudies-other
| S-EPMC5947497 | biostudies-literature
| S-EPMC3011422 | biostudies-other
| S-EPMC3998421 | biostudies-literature
| S-EPMC3006879 | biostudies-other
| S-EPMC3247605 | biostudies-literature
| S-EPMC4158506 | biostudies-other
| S-EPMC2977794 | biostudies-literature
| S-EPMC3414984 | biostudies-literature