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Catena-Poly[[zinc-?-[2-(2-{[2-(2-hy-droxy-benzo-yl)hydrazinyl-idene]meth-yl}phen-oxy)acetato-(2-)]] monohydrate].

ABSTRACT: In the title compound, {[Zn(C(16)H(12)N(2)O(5))]·H(2)O}(n), the unique Zn(II) ion is coordinated in a distorted square-pyramidal environment by three O atoms and one N atom from a symmetry-unique ligand. A symmetry-related ligand provides an O atom from a carboxyl-ate group to complete the coordination in the apical site and generate a one-dimensional polymer parallel to [010]. In addition to an intra-molecular O-H?N hydrogen bond, inter-molecular O-H?O and weak C-H?O hydrogen bonds are observed within the one-dimensional structure.

SUBMITTER: Luo F

PROVIDER: S-EPMC3247530 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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catena-Poly[[zinc-μ-[2-(2-{[2-(2-hy-droxy-benzo-yl)hydrazinyl-idene]meth-yl}phen-oxy)acetato-(2-)]] monohydrate].

Luo Feihua F Yang Li L Zhang Ping P Liu Dan D

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title compound, {[Zn(C(16)H(12)N(2)O(5))]·H(2)O}(n), the unique Zn(II) ion is coordinated in a distorted square-pyramidal environment by three O atoms and one N atom from a symmetry-unique ligand. A symmetry-related ligand provides an O atom from a carboxyl-ate group to complete the coordination in the apical site and generate a one-dimensional polymer parallel to [010]. In addition to an intra-molecular O-H⋯N hydrogen bond, inter-molecular O-H⋯O and weak C-H⋯O hydrogen bonds are observed ...[more]

PMID: 22219835

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