Unknown

Dataset Information

0

Bis[5-(4-bromo-phen-yl)-4-(tert-but-oxy-carbon-yl)pyrrolidine-2-carboxyl-ato]copper(II) dihydrate.

ABSTRACT: In the title compound, [Cu(C(16)H(19)BrNO(4))(2)]·2H(2)O, the Cu(II) ion resides on an inversion centre and is coordinated by two O and two N atoms from two enanti-omeric 5-(4-bromo-phen-yl)-4-(tert-but-oxy-carbon-yl)pyrrolidine-2-carboxyl-ate ligands in a distorted square-planar geometry. The relative stereochemistry of the three stereogenic C atoms in each ligand has been determined. In the crystal, inter-molecular N-H?O and O-H?O hydrogen bonds link the mol-ecules into layers parallel to the bc plane. The crystal studied was twinned by pseudo-merohedry with twin fractions of 0.719?(3) and 0.281?(3).

SUBMITTER: Kudryavtsev KV 

PROVIDER: S-EPMC3247543 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis[5-(4-bromo-phen-yl)-4-(tert-but-oxy-carbon-yl)pyrrolidine-2-carboxyl-ato]copper(II) dihydrate.

Kudryavtsev Konstantin V KV   Churakov Andrei V AV   Dogan Ozdemir O  

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title compound, [Cu(C(16)H(19)BrNO(4))(2)]·2H(2)O, the Cu(II) ion resides on an inversion centre and is coordinated by two O and two N atoms from two enanti-omeric 5-(4-bromo-phen-yl)-4-(tert-but-oxy-carbon-yl)pyrrolidine-2-carboxyl-ate ligands in a distorted square-planar geometry. The relative stereochemistry of the three stereogenic C atoms in each ligand has been determined. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the mol-ecules into layers parallel to the  ...[more]

Similar Datasets

Unknown Di-tert-butyl-chlorido(pyrrolidine-1-dithio-carboxyl-ato-κS,S')tin(IV).
| S-EPMC2914963 | biostudies-literature
Unknown Ethyl 1-(2-bromo-eth-yl)-3-(4-meth-oxy-phen-yl)-1H-pyrazole-5-carboxyl-ate.
| S-EPMC3414964 | biostudies-literature
Unknown 1-(4-Meth-oxy-phen-yl)pyrrolidine-2,5-dione.
| S-EPMC3884492 | biostudies-literature
Unknown (2,2'-Bipyridine)bis-(3-carboxy-pyrazine-2-carboxyl-ato)copper(II) dihydrate.
| S-EPMC2961978 | biostudies-literature
Unknown (5-Bromo-2-methyl-phen-yl)(4-eth-oxy-phen-yl)methanone.
| S-EPMC3007335 | biostudies-literature
Unknown Ethyl 1-tert-butyl-2-(4-hydr-oxy-3-methoxy-phen-yl)-1H-benzimidazole-5-carboxyl-ate.
| S-EPMC2979157 | biostudies-literature
Unknown tert-Butyl 4-{5-[3-(tri-fluoro-meth-oxy)phen-yl]-1,2,4-oxa-diazol-3-yl}piperazine-1-carboxyl-ate.
| S-EPMC3648287 | biostudies-literature
Unknown Methyl 3-(4-bromo-phen-yl)-2-(1H-indol-3-ylmeth-yl)-5-[1-(4-methoxy-phen-yl)-4-oxo-2-phenyl-azetidin-2-yl]-4-nitro-pyrrolidine-2-carboxyl-ate.
| S-EPMC2961354 | biostudies-literature
Unknown (2R,4R)-1-(tert-But-oxy-carbon-yl)-4-meth-oxy-pyrrolidine-2-carb-oxy-lic acid.
| S-EPMC3011444 | biostudies-literature
Unknown (E)-1-(4-Bromo-phen-yl)-2-(4-tert-butyl-phen-yl)-1-phenyl-ethene.
| S-EPMC2960472 | biostudies-literature