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4-Chloro-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide methanol monosolvate.

ABSTRACT: The title compound, C(15)H(13)ClN(2)O(3)·CH(3)OH, was synthesized by the condensation reaction of 2-hy-droxy-4-meth-oxy-benzaldehyde with 4-chloro-benzohydrazide in methanol. The Schiff base mol-ecule displays a trans configuration with respect to the C=N and C-N bonds. The dihedral angle between the two benzene rings is 5.3?(2)°. In the crystal, mol-ecules are linked by N-H?O and O-H?O hydrogen-bond inter-actions into chains running parallel to the a axis. An intra-molecular O-H?N hydrogen bond is observed.

SUBMITTER: Zhi F

PROVIDER: S-EPMC3247565 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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4-Chloro-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide methanol monosolvate.

Zhi Feng F Wang Rong R Zhang Yi Y Wang Qiang Q Yang Yi-Lin YL

Acta crystallographica. Section E, Structure reports online 20111005 Pt 11

The title compound, C(15)H(13)ClN(2)O(3)·CH(3)OH, was synthesized by the condensation reaction of 2-hy-droxy-4-meth-oxy-benzaldehyde with 4-chloro-benzohydrazide in methanol. The Schiff base mol-ecule displays a trans configuration with respect to the C=N and C-N bonds. The dihedral angle between the two benzene rings is 5.3 (2)°. In the crystal, mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen-bond inter-actions into chains running parallel to the a axis. An intra-molecular O-H⋯N hydrogen bond ...[more]

PMID: 22219870

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