Unknown

Dataset Information

0

8-{[(E)-3-(2-Chloro-phen-yl)acrylo-yloxy]imino}-12,13-ep-oxy-trichethec-9-en-4-yl (E)-3-(2-chloro-phen-yl)acrylate.

ABSTRACT: In the title compound, C(33)H(31)Cl(2)NO(6), the five-membered ring displays an envelope conformation, whereas the two six-membered rings both exhibit a chair conformation. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 69.08?(4)°, and these two mean planes are nearly perpendicular to the ep-oxy ring, making dihedral angles of 87.53?(4) and 88.67?(4)°, respectively.

SUBMITTER: Xu XJ 

PROVIDER: S-EPMC3247573 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

8-{[(E)-3-(2-Chloro-phen-yl)acrylo-yloxy]imino}-12,13-ep-oxy-trichethec-9-en-4-yl (E)-3-(2-chloro-phen-yl)acrylate.

Xu Xiao-Jun XJ   Li Xiao-Liang XL   Cheng Jing-Li JL   Zhao Jin-Hao JH  

Acta crystallographica. Section E, Structure reports online 20111005 Pt 11

In the title compound, C(33)H(31)Cl(2)NO(6), the five-membered ring displays an envelope conformation, whereas the two six-membered rings both exhibit a chair conformation. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 69.08 (4)°, and these two mean planes are nearly perpendicular to the ep-oxy ring, making dihedral angles of 87.53 (4) and 88.67 (4)°, respecti  ...[more]

Similar Datasets

Unknown Trichodermin (12,13-ep-oxy-trichethec-9-en-4?-yl 4-fluoro-benzoate).
| S-EPMC3007378 | biostudies-literature
Unknown (E)-Methyl 3-(4-chloro-phen-yl)-2-{2-[(E)-(hy-droxy-imino)-meth-yl]phen-oxy-meth-yl}acrylate.
| S-EPMC3201559 | biostudies-literature
Unknown (E)-1-(4-Chloro-phen-yl)-3-[4-(2,3,4,6-tetra-O-acetyl-?-d-allopyranos-yloxy)phen-yl]prop-2-en-1-one.
| S-EPMC2979931 | biostudies-literature
Unknown 4-Chloro-2-[(E)-(2-chloro-phen-yl)imino-meth-yl]phenol.
| S-EPMC2968492 | biostudies-literature
Unknown 2-Chloro-4-{(E)-[(4-chloro-phen-yl)imino]-meth-yl}phenol.
| S-EPMC3295463 | biostudies-literature
Unknown 2-{[3-Chloro-4-(4-chloro-phen-oxy)phen-yl]imino-meth-yl}-4-nitro-phenol.
| S-EPMC3685046 | biostudies-literature
Unknown Ethyl 2-(4-chloro-phen-yl)-3-(3,5-dimethoxy-phen-oxy)acrylate.
| S-EPMC2959914 | biostudies-literature
Unknown 2-[(4-Chloro-phen-yl)imino-meth-yl]hydro-quinone.
| S-EPMC2977821 | biostudies-literature
Unknown (E)-4-{2-[(4-Chloro-phen-yl)imino-meth-yl]phen-oxy}phthalonitrile.
| S-EPMC2977715 | biostudies-literature
Unknown (Z)-Isobutyl 2-benzamido-3-(4-chloro-phen-yl)acrylate.
| S-EPMC2970985 | biostudies-literature