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8-{[(E)-3-(2-Chloro-phen-yl)acrylo-yloxy]imino}-12,13-ep-oxy-trichethec-9-en-4-yl (E)-3-(2-chloro-phen-yl)acrylate.

ABSTRACT: In the title compound, C(33)H(31)Cl(2)NO(6), the five-membered ring displays an envelope conformation, whereas the two six-membered rings both exhibit a chair conformation. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 69.08?(4)°, and these two mean planes are nearly perpendicular to the ep-oxy ring, making dihedral angles of 87.53?(4) and 88.67?(4)°, respectively.

SUBMITTER: Xu XJ 

PROVIDER: S-EPMC3247573 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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8-{[(E)-3-(2-Chloro-phen-yl)acrylo-yloxy]imino}-12,13-ep-oxy-trichethec-9-en-4-yl (E)-3-(2-chloro-phen-yl)acrylate.

Xu Xiao-Jun XJ   Li Xiao-Liang XL   Cheng Jing-Li JL   Zhao Jin-Hao JH  

Acta crystallographica. Section E, Structure reports online 20111005 Pt 11

In the title compound, C(33)H(31)Cl(2)NO(6), the five-membered ring displays an envelope conformation, whereas the two six-membered rings both exhibit a chair conformation. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 69.08 (4)°, and these two mean planes are nearly perpendicular to the ep-oxy ring, making dihedral angles of 87.53 (4) and 88.67 (4)°, respecti  ...[more]

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