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2,4-Dichloro-N-(3,5-dimethyl-phen-yl)benzene-sulfonamide.


ABSTRACT: In the crystal of the title compound, C(14)H(13)Cl(2)NO(2)S, the N-H bond in the C-SO(2)-NH-C segment is syn to one of the meta-methyl groups in the aniline benzene ring and anti to the other. Further, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to the S=O bonds. The C-SO(2)-NH-C torsion angle is 54.9?(2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 82.8?(1)°. The crystal structure features inversion-related dimers linked by pairs of N-H?O hydrogen bonds. There are also weak C-H?O hydrogen bonds between these dimers.

SUBMITTER: Rodrigues VZ 

PROVIDER: S-EPMC3247580 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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2,4-Dichloro-N-(3,5-dimethyl-phen-yl)benzene-sulfonamide.

Rodrigues Vinola Z VZ   Foro Sabine S   Gowda B Thimme BT  

Acta crystallographica. Section E, Structure reports online 20111005 Pt 11


In the crystal of the title compound, C(14)H(13)Cl(2)NO(2)S, the N-H bond in the C-SO(2)-NH-C segment is syn to one of the meta-methyl groups in the aniline benzene ring and anti to the other. Further, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to the S=O bonds. The C-SO(2)-NH-C torsion angle is 54.9 (2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 82.8 (1)°. The crystal structure features inversion-related dimers linked b  ...[more]

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