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1-(5-Nitro-2-oxoindolin-3-yl-idene)thio-semicarbazide.

ABSTRACT: In the title molecule, C(9)H(7)N(5)O(3)S, there is an intramolecular N-H?O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135?(2)?Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N-H?O and N-H?S hydrogen bonds, forming two-dimensional networks lying parallel to (10[Formula: see text]). They are separated by an interplanar distance of 3.3214?(9)?Å, leading to ?-? interactions which stabilize the crystal structure.

SUBMITTER: Bandeira KC

PROVIDER: S-EPMC3247594 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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1-(5-Nitro-2-oxoindolin-3-yl-idene)thio-semicarbazide.

Bandeira Katlen C T KC Bresolin Leandro L Beck Johannes J Daniels Jörg J de Oliveira Adriano Bof AB

Acta crystallographica. Section E, Structure reports online 20111005 Pt 11

In the title molecule, C(9)H(7)N(5)O(3)S, there is an intramolecular N-H⋯O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135 (2) Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N-H⋯O and N-H⋯S hydrogen bonds, forming two-dimensional networks lying parallel to (10[Formula: see text]). They are separated by an interplanar distance of 3.3214 (9) Å, leading to π-π interactions which stabilize t ...[more]

PMID: 22219899

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