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(5E)-5-(2,4-Dichloro-benzyl-idene)-2-(piperidin-1-yl)-1,3-thia-zol-4(5H)-one.

ABSTRACT: In the title compound, C(15)H(14)Cl(2)N(2)OS, the piperidine ring adopts a chair conformation. The dihedral angle between the thia-zolidine ring and the dichloro-benzene ring is 9.30?(4)°; this near coplanar conformation is stabilized by the formation of an intra-molecular C-H?S hydrogen bond, which generates an S(6) ring. In the crystal, mol-ecules are linked by C-H?O hydrogen bonds, forming [001] chains. Weak ?-? inter-actions [centroid-centroid separation = 3.5460?(5)?Å] consolidate the structure.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3247615 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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(5E)-5-(2,4-Dichloro-benzyl-idene)-2-(piperidin-1-yl)-1,3-thia-zol-4(5H)-one.

Fun Hoong-Kun HK Hemamalini Madhukar M Lobo Prajwal L PL Prasad D Jagadeesh DJ Poojary Boja B

Acta crystallographica. Section E, Structure reports online 20111008 Pt 11

In the title compound, C(15)H(14)Cl(2)N(2)OS, the piperidine ring adopts a chair conformation. The dihedral angle between the thia-zolidine ring and the dichloro-benzene ring is 9.30 (4)°; this near coplanar conformation is stabilized by the formation of an intra-molecular C-H⋯S hydrogen bond, which generates an S(6) ring. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming [001] chains. Weak π-π inter-actions [centroid-centroid separation = 3.5460 (5) Å] consolidate the struc ...[more]

PMID: 22219920

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