Unknown

Dataset Information

0

Enantioselective synthesis of (+)-majusculone.


ABSTRACT: The first enantioselective synthesis of a chamigrane sesquiterpene, (+)-majusculone, has been completed. The quaternary center was generated asymmetrically by alkylidene carbene insertion, with retention of absolute configuration, from a diastereomerically pure ketal.

SUBMITTER: Taber DF 

PROVIDER: S-EPMC3248824 | biostudies-literature | 2007 May

REPOSITORIES: biostudies-literature

altmetric image

Publications

Enantioselective synthesis of (+)-majusculone.

Taber Douglass F DF   Sikkander M Inthikhab MI   Storck Pierre H PH  

The Journal of organic chemistry 20070421 11


The first enantioselective synthesis of a chamigrane sesquiterpene, (+)-majusculone, has been completed. The quaternary center was generated asymmetrically by alkylidene carbene insertion, with retention of absolute configuration, from a diastereomerically pure ketal. ...[more]

Similar Datasets

| S-EPMC6497086 | biostudies-literature
| S-EPMC5387676 | biostudies-literature
| S-EPMC2525511 | biostudies-literature
| S-EPMC3205941 | biostudies-other
| S-EPMC2790369 | biostudies-literature
| S-EPMC1948832 | biostudies-literature
| S-EPMC3359844 | biostudies-literature
| S-EPMC5647245 | biostudies-literature
| S-EPMC8517970 | biostudies-literature
| S-EPMC2528287 | biostudies-literature