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Enantioselective synthesis of (+)-majusculone.

ABSTRACT: The first enantioselective synthesis of a chamigrane sesquiterpene, (+)-majusculone, has been completed. The quaternary center was generated asymmetrically by alkylidene carbene insertion, with retention of absolute configuration, from a diastereomerically pure ketal.

SUBMITTER: Taber DF 

PROVIDER: S-EPMC3248824 | biostudies-literature | 2007 May

REPOSITORIES: biostudies-literature

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Enantioselective synthesis of (+)-majusculone.

Taber Douglass F DF   Sikkander M Inthikhab MI   Storck Pierre H PH  

The Journal of organic chemistry 20070421 11

The first enantioselective synthesis of a chamigrane sesquiterpene, (+)-majusculone, has been completed. The quaternary center was generated asymmetrically by alkylidene carbene insertion, with retention of absolute configuration, from a diastereomerically pure ketal. ...[more]

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