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Bis(?-di-2-pyridyl disulfide-?N,S:N')di-?(3)-iodido-di-?(2)-iodido-tetra-copper(I).

ABSTRACT: In the centrosymmetric tetra-nuclear title compound, [Cu(4)I(4)(C(10)H(8)N(2)S(2))(2)], there are two different Cu(I) atoms with tetra-hedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the second Cu(I) atom is coordinated by a pyridine-N and three I atoms. Iodine bridges between the Cu(I) atoms form a tetra-nuclear structure.

SUBMITTER: Wang YH

PROVIDER: S-EPMC3254296 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Bis(μ-di-2-pyridyl disulfide-κN,S:N')di-μ(3)-iodido-di-μ(2)-iodido-tetra-copper(I).

Wang Yu-Hong YH Zhu Xue-Hua XH

Acta crystallographica. Section E, Structure reports online 20111207 Pt 1

In the centrosymmetric tetra-nuclear title compound, [Cu(4)I(4)(C(10)H(8)N(2)S(2))(2)], there are two different Cu(I) atoms with tetra-hedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the second Cu(I) atom is coordinated by a pyridine-N and three I atoms. Iodine bridges between the Cu(I) atoms form a tetra-nuclear structure. ...[more]

PMID: 22259324

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