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1-Benzoyl-3-(2,4,5-trichloro-phen-yl)thio-urea.

ABSTRACT: The benzene and phenyl rings in the title compound, C(14)H(9)Cl(3)N(2)OS, form a dihedral angle of 40.98?(6)°. The mol-ecule exists in the thione form with typical thio-urea C-S [1.666?(2)?Å] and C-O [1.227?(3)?Å] bond lengths as well as shortened C-N bonds [1.345?(3) and 1.386?(2)?Å]. An intra-molecular N-H?O hydrogen bond stabilizes the mol-ecular conformation. In the crystal, pairs of N-H?S hydrogen bonds link the mol-ecules into centrosymmetric dimers.

SUBMITTER: Rauf MK

PROVIDER: S-EPMC3254466 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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1-Benzoyl-3-(2,4,5-trichloro-phen-yl)thio-urea.

Rauf M Khawar MK Ebihara Masahiro M Badshah Amin A Imtiaz-Ud-Din

Acta crystallographica. Section E, Structure reports online 20111214 Pt 1

The benzene and phenyl rings in the title compound, C(14)H(9)Cl(3)N(2)OS, form a dihedral angle of 40.98 (6)°. The mol-ecule exists in the thione form with typical thio-urea C-S [1.666 (2) Å] and C-O [1.227 (3) Å] bond lengths as well as shortened C-N bonds [1.345 (3) and 1.386 (2) Å]. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation. In the crystal, pairs of N-H⋯S hydrogen bonds link the mol-ecules into centrosymmetric dimers. ...[more]

PMID: 22259406

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