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1-(4,4''-Difluoro-5'-meth-oxy-1,1':3',1''-terphenyl-4'-yl)ethanone.

ABSTRACT: In the title compound, C(21)H(16)F(2)O(2), the central benzene ring is inclined at dihedral angles of 30.91?(8) and 46.88?(7)° to the two terminal fluoro-substituted rings. The dihedral angle between the two terminal fluoro-subsituted rings is 68.34?(8)°. An intra-molecular C-H?O hydrogen bond generates an S(6) ring motif. The crystal structure is stabilized by weak C-H?? inter-actions.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3254504 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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1-(4,4''-Difluoro-5'-meth-oxy-1,1':3',1''-terphenyl-4'-yl)ethanone.

Fun Hoong-Kun HK Hemamalini Madhukar M Samshuddin S S Samshuddin S S Narayana B B Sarojini B K BK

Acta crystallographica. Section E, Structure reports online 20111217 Pt 1

In the title compound, C(21)H(16)F(2)O(2), the central benzene ring is inclined at dihedral angles of 30.91 (8) and 46.88 (7)° to the two terminal fluoro-substituted rings. The dihedral angle between the two terminal fluoro-subsituted rings is 68.34 (8)°. An intra-molecular C-H⋯O hydrogen bond generates an S(6) ring motif. The crystal structure is stabilized by weak C-H⋯π inter-actions. ...[more]

PMID: 22259448

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Methyl 4,4''-difluoro-5'-meth-oxy-1,1':3',1''-terphenyl-4'-carboxyl-ate.

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