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(E)-4-[(3,5-Dimethyl-phen-yl)imino-meth-yl]-2-meth-oxy-3-nitro-phenol.

ABSTRACT: The mol-ecule of the title compound, C(16)H(16)N(2)O(4), exists in the E configuration with respect to the central C=N double bond. The dihedral angle between the two benzene rings is 2.17?(9)?Å. In the crystal, mol-ecules are linked via O-H?N hydrogen bonds into chains that propagate along the b-axis direction. There is also ?-? stacking of inversion-related mol-ecules, with inter-planar spacings of 3.479?(5)?Å and ring centroid-centroid distances of 3.876?(4)?Å.

SUBMITTER: Yang ZM

PROVIDER: S-EPMC3254553 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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(E)-4-[(3,5-Dimethyl-phen-yl)imino-meth-yl]-2-meth-oxy-3-nitro-phenol.

Yang Zhong-Ming ZM Su Deng-Cheng DC Zhu Hai-Liang HL

Acta crystallographica. Section E, Structure reports online 20111223 Pt 1

The mol-ecule of the title compound, C(16)H(16)N(2)O(4), exists in the E configuration with respect to the central C=N double bond. The dihedral angle between the two benzene rings is 2.17 (9) Å. In the crystal, mol-ecules are linked via O-H⋯N hydrogen bonds into chains that propagate along the b-axis direction. There is also π-π stacking of inversion-related mol-ecules, with inter-planar spacings of 3.479 (5) Å and ring centroid-centroid distances of 3.876 (4) Å. ...[more]

PMID: 22259502

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