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3-Hy-droxy-4-phenyl-1-(prop-2-en-1-yl)-2,3,4,5-tetra-hydro-1H-1,5-benzodiazepin-2-one.

ABSTRACT: The asymmetric unit of the title compound, C(18)H(18)N(2)O(2), contains three independent mol-ecules. In each, the seven-membered diazepine ring adopts a boat conformation with the hy-droxy-substituted C atom at the prow and fused-ring C atoms at the stern. In the crystal, the mol-ecules are linked by O-H?O and N-H?O hydrogen bonds. The allyl group of one mol-ecule is equally disordered over two positions.

SUBMITTER: Rida M

PROVIDER: S-EPMC3254569 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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3-Hy-droxy-4-phenyl-1-(prop-2-en-1-yl)-2,3,4,5-tetra-hydro-1H-1,5-benzodiazepin-2-one.

Rida Mohamed M Mamari Khalil K Essassi El Mokhtar el M Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20111223 Pt 1

The asymmetric unit of the title compound, C(18)H(18)N(2)O(2), contains three independent mol-ecules. In each, the seven-membered diazepine ring adopts a boat conformation with the hy-droxy-substituted C atom at the prow and fused-ring C atoms at the stern. In the crystal, the mol-ecules are linked by O-H⋯O and N-H⋯O hydrogen bonds. The allyl group of one mol-ecule is equally disordered over two positions. ...[more]

PMID: 22259519

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