Evidence for interstitial carbon in nitrogenase FeMo cofactor.
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ABSTRACT:
SUBMITTER: Spatzal T
PROVIDER: S-EPMC3268367 | biostudies-literature | 2011 Nov
REPOSITORIES: biostudies-literature
Publications
Evidence for interstitial carbon in nitrogenase FeMo cofactor.
Spatzal Thomas T Aksoyoglu Müge M Zhang Limei L Andrade Susana L A SL Schleicher Erik E Weber Stefan S Rees Douglas C DC Einsle Oliver O
Science (New York, N.Y.) 20111101 6058
The identity of the interstitial light atom in the center of the FeMo cofactor of nitrogenase has been enigmatic since its discovery. Atomic-resolution x-ray diffraction data and an electron spin echo envelope modulation (ESEEM) analysis now provide direct evidence that the ligand is a carbon species. ...[more]
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