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Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4).

ABSTRACT: The title compound, Li(3.5)Eu(1.5)(MoO(4))(4), was prepared by solid-state reactions. The fundamental building units of the structure are LiO(4) polyhedra (site symmetry [Formula: see text]), distorted LiO(6) polyhedra and MoO(4) tetra-hedra, which are further inter-connected via corner-sharing O atoms. One site is occupied by both Li and Eu atoms in a substituent disordered manner (0.25:0.75), and the Li/Eu atoms are coordinated by eight O atoms in a distorted square-antiprismatic manner.

SUBMITTER: Zhao D

PROVIDER: S-EPMC3274837 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4).

Zhao Dan D Zhu Jing J Liang Peng P Chang Huan H He Rong R

Acta crystallographica. Section E, Structure reports online 20120111 Pt 2

The title compound, Li(3.5)Eu(1.5)(MoO(4))(4), was prepared by solid-state reactions. The fundamental building units of the structure are LiO(4) polyhedra (site symmetry [Formula: see text]), distorted LiO(6) polyhedra and MoO(4) tetra-hedra, which are further inter-connected via corner-sharing O atoms. One site is occupied by both Li and Eu atoms in a substituent disordered manner (0.25:0.75), and the Li/Eu atoms are coordinated by eight O atoms in a distorted square-antiprismatic manner. ...[more]

PMID: 22346790

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