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(E)-1-(3-Eth-oxy-2-hy-droxy-benzyl-idene)thio-semicarbazide.

ABSTRACT: The title compound, C(10)H(13)N(3)O(2)S, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. In the crystal, the A and B mol-ecules are linked via pairs of N-H?O and O-H?S hydrogen bonds, forming dimers with R(2) (2)(14) and R(2) (2)(6) ring motifs. These dimers are linked via a pair of N-H?S hydrogen bonds with an R(2) (2)(8) ring motif, forming chains propagating along the c-axis direction. The crystal was refined as an inversion twin with a final BASF ratio of 0.54?(11):0.46?(11).

SUBMITTER: Adabi Ardakani A

PROVIDER: S-EPMC3275025 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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(E)-1-(3-Eth-oxy-2-hy-droxy-benzyl-idene)thio-semicarbazide.

Adabi Ardakani Amir A Kargar Hadi H Kia Reza R Tahir Muhammad Nawaz MN

Acta crystallographica. Section E, Structure reports online 20120111 Pt 2

The title compound, C(10)H(13)N(3)O(2)S, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. In the crystal, the A and B mol-ecules are linked via pairs of N-H⋯O and O-H⋯S hydrogen bonds, forming dimers with R(2) (2)(14) and R(2) (2)(6) ring motifs. These dimers are linked via a pair of N-H⋯S hydrogen bonds with an R(2) (2)(8) ring motif, forming chains propagating along the c-axis direction. The crystal was refined as an inversion twin with a final BASF ratio of 0.54 ...[more]

PMID: 22346970

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