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1,3-Bis(biphenyl-4-yl)-2,2-dibromo-3-oxopropyl acetate.

ABSTRACT: In the title compound, C(29)H(22)Br(2)O(3), the dihedral angles between the mean planes of the benzene rings within each biphenyl group are 26.7?(8) and 30.9?(8)°. The mean planes of the terminal and inner benzene rings of the biphenyl groups bonded through a propan-1-one group in the V-shaped mol-ecule are oriented at angles of 66.1?(7) and 60.0?(8)°, respectively. The two Br atoms are opposite the propen-1-one group. Weak inter-molecular C-H?O and C-H?? inter-actions are observed in the crystal structure.

SUBMITTER: Jasinski JP

PROVIDER: S-EPMC3275044 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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1,3-Bis(biphenyl-4-yl)-2,2-dibromo-3-oxopropyl acetate.

Jasinski Jerry P JP Golen James A JA Siddaraju B P BP Narayana B B Yathirajan H S HS

Acta crystallographica. Section E, Structure reports online 20120111 Pt 2

In the title compound, C(29)H(22)Br(2)O(3), the dihedral angles between the mean planes of the benzene rings within each biphenyl group are 26.7 (8) and 30.9 (8)°. The mean planes of the terminal and inner benzene rings of the biphenyl groups bonded through a propan-1-one group in the V-shaped mol-ecule are oriented at angles of 66.1 (7) and 60.0 (8)°, respectively. The two Br atoms are opposite the propen-1-one group. Weak inter-molecular C-H⋯O and C-H⋯π inter-actions are observed in the crysta ...[more]

PMID: 22346989

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